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Occupational and Environmental Safety

3D Printer Safety

Overview

Recently, 3D printers, an additive manufacturing technology, have been increasing in both popularity and affordability. They are being used in laboratories, offices, shops, and also in residential locations (dorm rooms and apartments).  In some 3D printing processes, thermoplastics are heated, nozzle extruded and then deposited onto a surface to build the object. Since most 3D printers do not have exhaust ventilation or filtration accessories, placement of the printer and selection of printing materials must both be carefully considered. There are both chemical and physical hazards associated with 3D printers, which are determined by the type of printer, chemicals used for print materials, and parts finishing process:

 These hazards include:

  • The generation of ultrafine/nano-sized particles (UFP);
  • Chemical vapors (ex. styrene, acrylonitrile, or formaldehyde, etc.) depending on the media being used.
  • Generation of Heat and contact hot surfaces:
  • Mechanical hazards from moving parts;
  • High voltage;
  • Ultraviolet light;
  • Use of tools to remove and finish parts

3D Printer Safety Guidelines

The following is a list of safety precautions that need to be considered when using a 3D printer:

  1. All 3D Printers must be registered in BioRAFT/SciShield
  2. All 3D printers must be placed in a well-ventilated area and/or directly ventilated to the outside, regardless of the printing materials that will be used. . Air exchanges of at least 4-6 per hour are recommended for the adequate ventilation for up to 4 desk top printers.
  3. Whenever possible, purchase 3D printer models that are enclosed. (Full enclosure appears more effective at controlling UFP emissions than a cover)
  4. Any 3D printer that is larger than a desk top model please contact OES to conduct a risk assessment.
  5. Always use the manufacturer’s supplied controls and follow manufacturer’s instructions for set up and operation.
  6. When 3D printers are running, users should not congregate around the printing operation to minimize the inhalation of particulates being created.
  7. Maintain a distance from the printer to minimize breathing in emitted particles and choose a low-emitting printer and filament when possible;
  8. Whenever possible, 3D printers that utilize resins and/or corrosives should be placed in areas designed as labs or shops that have eyewashes and safety showers
  9. If the printer nozzle jams, turn off the printer and allow it to ventilate before removing the cover;
  10. Wash hands thoroughly after working with 3D printers.
  1. There shall be no eating, drinking, applying cosmetics, chewing gum, or handling contact lenses in rooms that contain 3D printing operations.
  1. All work surfaces must be cleaned by a wet method. Sweeping and other dry methods can create airborne particles.
  2. All 3D metal printing operations must be assessed on a case-by-case basis by Occupational and Environmental Safety.
  3. If you use a material other than PLA or using experimental materials while printing, please contact OES to conduct a risk assessment.
  4. TRAINING : Anyone that works with a 3D printer needs to take Lab safety training (for Research labs)  or Hazard Communication (non-researcher areas), training.

3D Printer Types


FDM

  • FDM is the most widely-used 3D printing technology. The thermoplastic filament materials is melted to build up the layers on a platform to create a 3D object.

PLA & ABS

  • PLA (Polylactic Acid) and ABS (Acrylonitrile Butadiene Styrene) are the most popular materials used in FDM 3D printers.

SLA

  • SLA is a prototyping process technology. The liquid form of photopolymer resin is solidified by applying the ultraviolet (UV) light to create a 3D object layer-by-layer. The object usually follows by a chemical bath and a post-cure in an ultra violet oven processes.

Printing Materials

There are a variety of printing materials available for use with 3D printers, each with its own inherent hazards. The two most commonly used materials are Polylactic Acid (PLA) and Acrylonitrile Butadiene Styrene (ABS). In general, PLA is much safer to use than ABS.

Each 3D printer has been designed to use certain types of materials. These materials have inherent hazards and may become more hazardous when they are subjected to the 3D printing process or are inadvertently ignited.

Please review product Safety Data Sheets (SDSs) within SciShield for material specific safety information before using anything in a 3D printer.

Thermoplastics

Thermoplastics can be flammable, cause irritation and skin sensitivity. Some may contain small amounts of toxic components. Photopolymers utilize exposure to UV light to harden during the printing process. These often contain hazardous monomers, such as acrylates. Additionally, UV light used for the curing process is a radiation hazard, which can cause damage to vision and skin.

Support Materials

The 3D printing process often utilizes a support material to allow for creation of the empty spaces in the fabrication design. Support materials often contain harmful chemicals, such as phenyl phosphates, that are incorporated into the thermoplastic acrylic polymer, and thus are hazardous during use and disposal.

Metal Materials

Reactive and highly combustible powder metals are used in the fabrication of 3D-printed metal alloy tools and parts. Finely divided metal powders, such as titanium and aluminum, can spontaneously combust causing fires (pyrophoric). This process uses very high heat which may expose users to thermal injury, as well as potential inhalation of the powders. Standard Operating Procedures (SOPs) are required for operation of this type of 3D Printer.

Consult the OES Industrial Hygiene manager for a process Risk Assessment prior to using metal powders.

Corrosive Baths for Finishing Parts

  1. Corrosive baths shall only be used in a designated lab space only.
  2. Wear Personal Protective Equipment (PPE) including: lab coat or apron, chemical resistant gloves, and safety goggles when handling the chemical, placing an item in, or removing it from the bath.
  3. Ensure there is an eyewash in the vicinity of the bath, in case of a splash.
  4. Use tongs when placing an item in, or removing it from, the bath.
  5. Ensure tank is properly labeled with the chemical name and associated hazards.
  6. Ensure there is proper ventilation in the area where the bath is located.
  7. Do not pour any chemical down the drain. All used chemicals must be disposed of as hazardous waste.
  8. Anyone that works with the corrosive bath must take Hazardous Waste training.
  9. Caustic Soda is corrosive and can cause chemical burns, scarring and blindness.
  10. Mixing it with water generates heat that could ignite other materials.
  11. Sodium hydroxide should always be added to water and not vice versa.

Desktop FDM 3D Printer Set-Up

Hazards

  • Hot surfaces (print head; freshly printed plastic, heated bed)—fire or burn hazard
  • Moving parts—pinch point or entanglement hazard
  • Particulate emissions—Ultrafine particles have been found to be a health hazard with  PLA emissions being lower than what is emitted with ABS.
  • Electricity— shock or fire hazard

 

 

Reviewing New Equipment

  • Printer should be labeled in local language with warnings for “hot surfaces” and “moving parts” and these labels should be visible in operation.  If printer does not come properly labeled, make and apply them.
  • Heated printer beds above 80°C/176°F must be guarded from accidental touch.
  • If plan is to print unattended, confirm printer has an overheat sensor to prevent fires.  If there is no overheat sensor provided (or not installed such as with a DIY 3D printers), this must be labeled with the following in local language “Printer does not have an overheat sensor and CANNOT be left UNATTENDED”.  This rule must be strictly followed (see picture to right).
  • Identify location for the printer with the following:
    • Power outlets and/or data cables, as needed.
    • Fire protection systems including fire sprinklers, smoke alarm, and a fire extinguisher nearby.  If unable to provide all of these, review with RS.
    • Printers operating with non-biodegradable plastics (ABS) cannot be located near employee desks unless they are completely enclosed (sealed) while operating to limit particulate generation in the office.
  • Confirm location of printer operation and plastic reel storage with facilities (Note: When printer is in use, spool should be able to be located where it can freely turn).
  • Establish who will maintain equipment and who will be allowed to use it.
  • Keep a copy of the local SDS on-site for any material used.
  • Operate printer and create awesome things!