Publications
Below is a collection of selected journal papers and peer-reviewed conference papers, as well as a link to our Google Scholar page and ResearchGate page.
Archives
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2025
Duffy J. H.; Birkner N.; C. Kim C.; Jacobs R.; Morgan D.; Sharma S.; Misture S. T.; Kelder E. M.; Abernathy H. W. and Brinkman K., Structural and Thermodynamic analysis of triple-conducting ceramic materials BaCo0.4Fe0.4Zr0.2-xYxO3-δ. J. Mater. Chem. A, 2025, 13, 10147-10159.
Eisawi K.; Lani E.; Chong S.; Liezer M.; Tang M.; Brinkman K. S.; Riley B. J.; Naguib M., Nanohybrid of Silver-MXene: A Promising Sorbent for Gas Capture from Nuclear Waste. Adv. Mater. Interfaces, 2025, 2500011.
Zhao M.; Chen X.; Zhu H.; Xia S.; Ma Y.; Brinkman K.; Tong Z., Unraveling Cs substitution-induced evolution in Fe-hollandite: Linking crystal chemistry to leaching resistance. Journal of the American Ceramic Society, 2025, 108 (7), e20447.
Huang H.; Zhou T.; Conrad J.; Zou M.; Mu S.; Tang J.; Meng Y.; Zhao Z.; Peng F.; Xiao H.; Brinkman K.; Tong J., Scalable, durable, and high-performance protonic ceramic fuel cell stacks manufactured by direct laser reactive additive manufacturing. Device, 2025, 100840. -
2024
Cassell, N. S.; Birkner, N.; Mishra, A. K.; Jadhav, S.; Mofrad, A. M.; Bessmann, T. M.; Amoroso, J. W.; Li, Y.; Wang, L.; Brinkman, K. S. A-Site Occupancy Effects on Structure, Ionic Conductivity, and Thermodynamic Stability of KxMgx/2Ti8−x/2O16. MRS Advances 2024, 9 (7), 444–448.
Birkner, N.; Proust, V.; Schaeperkoetter, J.; Ta, A. T.; Gossard, A.; Daouli, A.; Badawi, M.; Cassell, N.; Misture, S.; Phillpot, S. R.; Zur Loye, H.-C.; Brinkman, K. S.; Grandjean, A. Microstructure, Adsorption Site Energetics, and Formation Enthalpy Control for FAU-Zeolite Cs+ Exchange. Microporous and Mesoporous Materials 2024, 373, 113110.
Dandeneau, C. S.; Rajeev, R.; Gootgeld, A.; Hitchcock, D. A.; Olson, L. C.; Zhou, T.; Tong, J.; Brinkman, K. S.; Garcia-Diaz, B. L. Structural Stability and Electrochemical Response of 3D Printed and Reactively Sintered Ga-Doped Li7La3Zr2O12 Electrolytes. Materials Letters 2024, 375, 137240.
Mishra, A. K.; Willoughby, J.; Estes, S. L.; Kohler, K. C.; Brinkman, K. S. Impact of Morphology and Oxygen Vacancy Content in Ni, Fe, Co-Doped Ceria for Efficient Electrocatalyst-Based Water Splitting.Nanoscale Adv. 2024, 6 (18), 4672–4682.
Mofrad, A. M.; Christian, M. S.; Schorne-Pinto, J.; Amoroso, J.; Brinkman, K. S.; Zur Loye, H.-C.; Besmann, T. M. Predictive Phase Stability of Actinide-Bearing Hollandite Waste Forms from First-Principles Calculations. Journal of Nuclear Materials 2024, 600, 155291.
Tuffy, B. W.; Birkner, N. R.; Schorne-Pinto, J.; Davis, R. C.; Mofrad, A. M.; Dixon, C. M.; Aziziha, M.; Christian, M. S.; Lynch, T. J.; Bartlett, M. T.; Besmann, T. M.; Brinkman, K. S.; Chiu, W. K. S. Formation of β-U 3 O 8 from UCl 3 Salt Compositions under Oxygen Exposure. J. Phys. Chem. B 2024, 128 (45), 11174–11185. -
2023
B. W. Tuffy, N. R. Birkner, J. Schorne-Pinto, R. C. Davis, A. M. Mofrad, C. M. Dixon, M. Aziziha, M. S. Christian, T. J. Lynch, M. T. Bartlett, T. M. Besmann, K. S. Brinkman, W. K. S. Chiu “Identification and Decomposition of Uranium Oxychloride Phases in Oxygen-Exposed UCl3 Salt Compositions", J. Phys. Chem. B 2023, 127, 27, 6091–6101.
Minda Zou, Jacob Conrad, Bridget Sheridan, Jiawei Zhang, Hua Huang, Shenglong Mu, Tianyi Zhou, Zeyu Zhao, Kyle S. Brinkman, Hai Xiao, Fei Peng, Jianhua Tong, "3D Printing Enabled Highly Scalable Tubular Protonic Ceramic Fuel Cells", ACS Energy Lett. 2023, 8, 8, 3545–3551.
J. H. Duffy, H. W. Abernathy, K. S. Brinkman, “Tuning proton kinetics in BaCo0.4 Fe0.4 Zr0.2–XYXO 3– d triple ionic-electronic conductors via aliovalent substitution”, J. Mater. Chem. A (2023).
C. S. Dandeneau, R. Rajeev, K. S. Brinkman, D. A. Hitchcock, B. L. Garcia-Diaz “Rapid fabrication of Ga-doped Li7La3Zr2O12 powder via microwave-assisted solution combustion synthesis”, Journal of Materials Sciences10853(2023)08397-4.
Y. Meng, H. Zheng, J. Duffy, H. Huang, K. He, J. Tong, K. S. Brinkman “Enhanced electrolysis performance through hierarchical nanoparticle formation in the BaCo0.4Fe0.4Zr0.1Y0.1O3-δ Cathode Materials System", Journal of Power Sources 560 (2023) 232724. -
2022
K. C. Park, P. Kittikhunnatham, J. Lim, G. C. Thaggard, Y. Liu, C. R. Martin, G. A. Leith, D. J. Toler, A. T. Ta, N. Birkner, I. L. Andino, A. H. Jimenez, G. Morrison, J. W. Amoroso, H. C. Z. Loye, D. P. DiPrete, M. D. Smith, K. S. Brinkman, S. R. Phillpot, N. B. Shustova “f-block MOFs: A Pathway to Heterometallic Transuranics” Angewandte Chemie International Edition2022;e202216349.
M. S. Christian, T. J. Lynch, J. Schorne-Pinto, A. M. Mofrad, N. R. Birkner, K. S. Brinkman, W. K. S. Chiu, T. M. Besmann. “Modeling Metallic Halide Local Structures in Salt Melts Using a Genetic Algorithm.” American Chemical Society (2022).
M. Ge, X. Huang, H. Yan, D. Gursoy, Y. Meng, J. Zhang, S Ghose, W. K. S. Chiu, K. S. Brinkman, Y. S. Chu “Three-dimensional imaging of grain boundaries via quantitative fluorescence X-ray tomography analysis" COMMUNICATIONS MATERIALS (2022) 3:37.
M. Zhao, N. Birkner, J. Schaeperkoetter, R. J. Koch, P. Russell, S. T. Misture, T. Besmann, J. Amoroso, K. Brinkman “Durable Cr-substituted (Ba,Cs)1.33(Cr,Ti)8O16hollandite waste forms with high Cs loading” Journal of the American Ceramic Society(2022).
T. J. Lynch, N. R. Birkner, M. S. Christian, J. A. Wrubel, J. Schorne-Pinto, A. V. Veelen, J. R. Bargar, T. M. Besmann, K. S. Brinkman, and W. K. S. Chiu “In Situ Determination of Speciation and Local Structure of NaCl− SrCl2 and LiF−ZrF4 Molten Salts” American Chemical Society(2022):126,7,1539–1550.
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2021
G. Chen, A. Feldhoff, A. Weidenkaff, C. Li, S. Liu, X. Zhu, J. Sunarso, K. Huang, X. Wu, A. F. Ghoniem, W. Yang, J. Xue, H. Wang, Z. Shao, J. H. Duffy, K. S. Brinkman, X. Tan, Y. Zhang, H. Jiang, R. Costa, K. A. Friedrich, and R. Kriegel “Roadmap on Sustainable Mixed Ionic-Electronic Conducting Membranes” Advanced Functional Materials(2021):2105702.
J. H. Duffy, Y. Meng, H. W. Abernathy and K. S. Brinkman. “Surface and Bulk Oxygen Kinetics of BaCo0.4Fe0.4Zr0.2−XYXO3−δ Triple Conducting Electrode Materials” Membranes (2021):11100766.
J. Gao, Y. Meng, J. H. Duffy, K. S. Brinkman. “Low-Temperature Protonic Ceramic Fuel Cells through Interfacial Engineering of Nanocrystalline BaCe0.7Zr0.1Y0.1Yb0.1O3-δElectrolytes” Advanced Energy and Sustainability Research (2021):2100098.
A. Ishii, H. Huang, Y. Meng, S. Mu, J. Gao, J. Lei, F. Peng, H. Xiao, J. Tong, K. S. Brinkman. “Chemically Inert Hydrocarbon-Based Slurries for Rapid Laser Sintering of Thin Proton-Conducting Ceramics” Materials Research Bulletin 143 (2021):111446.
Y. Meng, J. Duffy, B. T. Na, J. Gao, T. Yang, J. Tong, S. Lee, K. S. Brinkman. “Oxygen exchange and bulk diffusivity of BaCo0.4Fe0.4Zr0.1Y0.1O3-δ: Quantitative assessment of active cathode material for protonic ceramic fuel cells” Solid State Ionics 368 (2021): 115639.
N. Birkner, C. Li, S. L. Estes, K. S. Brinkman. “Gallium-Doping Effects on Structure, Lithium-Conduction, and Thermochemical Stability of Li7-3xGaxLa3Zr2O12 Garnet-Type Electrolytes” ChemSusChem 14 (2021): 1-11.
Z. Zhao, J Gao, Y. Meng, K.S. Brinkman, J. Tong. “Moderate temperature sintering of BaZr0.8Y0.2O3-δ protonic ceramics by A novel cold sintering pretreatment.” Ceramics International 47.8 (2021): 11313-11319.
M. Zhao, E. O’Quinn, N. Birkner, Y. Xu, M. Lang, K. Brinkman. “Radiation damage and thermal annealing in tunnel structured hollandite materials.” Acta Materialia 206 (2021): 116598.
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2020
S. Mu, Z. Zhao, H. Huang, J. Lei, F. Peng, H. Xiao, K.S. Brinkman, J. Tong. “Advanced Manufacturing of Intermediate-Temperature Protonic Ceramic Electrochemical Cells.” The Electrochemical Society Interface 29.4 (2020): 67.
C. Li, A. Ishii, L Roy, D. Hitchcock, Y. Meng, K. Brinkman. “Solid-state reactive sintering of dense and highly conductive Ta-doped Li7La3Zr2O12 using CuO as a sintering aid.” Journal of Materials Science 55.35 (2020): 16470-16481.
M. Zhao, J.W. Amoroso, K.M. Fenker, D.P. DiPrete, S. Misture, S. Utlak, T. Besmann, K. Brinkman. “The effect of cesium content on the thermodynamic stability and chemical durability of (Ba,Cs)1.33(Al,Ti)8O16 hollandite.” Journal of the American Ceramic Society 103.12 (2020): 7310-7321.
A. Ishii, S. Mu, Y. Meng, H. Huang, J. Lei, Y. Li, F. Peng, H. Xiao, J. Tong, K.S. Brinkman. “Rapid Laser Processing of Thin Sr‐Doped LaCrO3–δ Interconnects for Solid Oxide Fuel Cells.” Energy Technology 8.10 (2020): 2000364.
J. Gao, Y. Meng, A. Benton, J. He, L.G. Jacobsohn, J. Tong, K.S. Brinkman. “Insights into the Proton Transport Mechanism in TiO2 Simple Oxides by In Situ Raman Spectroscopy.” ACS Applied Materials & Interfaces 12.34 (2020): 38012-38018.
S. Mu, H. Huang, A. Ishii, Z. Zhao, M. Zou, P. Kuzbary, F. Peng, K.S. Brinkman, H. Xiao, J. Tong. “Rapid laser reactive sintering of BaCe0.7Zr0.1Y0.1Yb0.1O3-δ electrolyte for protonic ceramic fuel cells.” Journal of Power Sources Advances 4 (2020): 100017.
J. Gao, Y. Liu, Y. Meng, M. Hu, K. S. Brinkman, ”Fluoride-Based Anion Doping: A New Strategy for Improving the Performance of Protonic Ceramic Conductors of the FormBaZrO3” ChemElectroChem 2020, 7, 2242.
S. Mu, H. Huang, A. Ishii, Y. Hong, A. Santomauro, Z. Zhao, M. Zou, F. Peng, K.S. Brinkman, H. Xiao, J. Tong. “Rapid Laser Reactive Sintering for Sustainable and Clean Preparation of Protonic Ceramics.” ACS Omega 5.20 (2020): 11637-11642.
S. Mu, Y. Hong, H. Huang, A. Ishii, J. Lei, Y. Song, Y. Li, K.S. Brinkman, F. Peng, H. Xiao, J. Tong. “A Novel Laser 3D Printing Method for the Advanced Manufacturing of Protonic Ceramics.” Membranes 10.5 (2020): 98.
M. Zhao, P. Russell, J. Amoroso, S. Misture, S. Utlak, T. Besmann, L. Schuller-Nickles, K.S. Brinkman. “Exploring the links between crystal chemistry, cesium retention, thermochemistry and chemical durability in single-phase (Ba,Cs)1.33(Fe,Ti)8O16 hollandite.” Journal of Materials Science 55.15 (2020): 6401-6416.
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2019
O. A. Ejegbavwo, C. R. Martin, O. A. Olorunfemi, G. A. Leith, R. T. Ly, A. M. Rice, E. A. Dolgopolova, M. D. Smith, S.G. Karakalos, N. Birkner, B. A. Powell, S. Pandey, R. J. Koch, S. T. Misture, H. C. Z Loye, S. R. Phillpot, K. S. Brinkman, N. B. Shustova “Thermodynamics and Electronic Properties of Heterometallic Multinuclear Actinide-Containing Metal−Organic Frameworks with “Structural Memory”” American Chemical Society, 2019, 141, 11628−11640.
Y. Wu, A.W. Darge, A.A. Trofimov, C. Li, K.S. Brinkman, S.M. Husson, L.G. Jacobsohn, “Fabrication and characterization of ZnS:Ag-based ultrafiltration membrane scintillator” Optical Materials, 2019, 88, 424-428.
P.J.C. Damian, A.P. Cocco, J.A. Wrubel, T. Hong, R.K. Bordia, Y. Liu, P. Pianetta, J.W. Amoroso, K.S. Brinkman, W.K.S. Chiu, “Simultaneous Three‐Dimensional Elemental Mapping of Hollandite and Pyrochlore Material Phases in Ceramic Waste Form Materials” Journal of the American Ceramic Society, 2019.
Z. Chen, T. Hong, Z. Wang, J. Wang, H. Huang, R. Peng, W. Yan, Z. Fu, K.S. Brinkman, Y. Lu, “Anisotropic magnetic property and exchange bias effect in a homogeneous Sillen-Aurivillius layered oxide” Journal of the European Ceramic Society, 2019.
J. Gao, Y. Meng, T. Hong, S. Kim, S. Lee, K. He, K.S. Brinkman, “Rational anode design for protonic ceramic fuel cells by a one-step phase inversion method”, Journal of Power Sources, 2019, 418, 162-166.
Y. Meng, L. Sun, J. Gao, W. Tan, C. Chen, J. Yi, H.J.M. Bouwmeester, Z. Sun, K.S. Brinkman, “Insights into the CO2 Stability-Performance Trade-Off of Antimony-Doped SrFeO3−δ Perovskite Cathode for Solid Oxide Fuel Cells”, ACS Applied Materials & Interfaces, 2019.
R. Grote, T. Hong, L. Shuller-Nickles, J. Amoroso, M. Tang, K.S. Brinkman, “Radiation tolerant ceramics for nuclear waste immobilization: Structure and stability of cesium containing hollandite of the form (Ba,Cs)1.33(Zn,Ti)8O16 and (Ba,Cs)1.33(Ga,Ti)8O16“, Journal of Nuclear Materials, 2019, 518, 166-176.
Y. Meng, J. Gao, Z. Zhao, J. Amoroso, J. Tong, K.S. Brinkman, “Review: recent progress in low-temperature proton-conducting ceramics”, Journal of Materials Science, 2019.
S.A. Utlak, T.M. Besmann, K.S. Brinkman, J.W. Amoroso, “Thermodynamic assessment of hollandite high-level radioactive waste form”, Journal of the American Ceramic Society, 2019, 1-14.
Y. Meng, J. Gao, H. Huang, M. Zou, J. Duffy, J. Tong, K.S. Brinkman, “A high-performance reversible protonic ceramic electrochemical cell based on a novel Sm-doped BaCe0· 7Zr0· 1Y0· 2O3-δ electrolyte”, Journal of Power Sources, 2019, 439, 227093.
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2018
M. Zhao, Y. Xu, L. Shuller-Nickles, J. Amoroso, A.I. Frenkel, Y. Li, W. Gong, K Lilova, A. Navrotsky, K.S. Brinkman, “Compositional control of radionuclide retention in hollandite‐based ceramic waste forms for Cs‐immobilization”, Journal of the American Ceramic Society, 2018.
K.S. Brinkman, “An Interdisciplinary View of Interfaces Perspectives Regarding Emergent Phase Formation”, Journal of Electrochemical Energy Conversion and Storage, 2017, 15, 0110003-1, doi:10.1115/1.4037583.
C.S. Dandeneau, T. Hong, K.S. Brinkman, E.R. Vance, J.W. Amoroso, “Comparison of structure, morphology, and leach characteristics of multi-phase ceramics produced via melt processing and hot isostatic pressing”, Journal of Nuclear Materials, 2018, 502, 113-122.
H. Yan, N. Bouet, J. Zhou, X. Huang, E. Nazaretski, W. Xu, A.P. Cocco, W.K.S. Chiu, K.S. Brinkman, Y.S. Chu, “Multimodal hard x-ray imaging with resolution approaching 10 nm for studies in material science”, Nano Futures, 2018, 2 (1), 011001.
Y. Wen, Y. Xu, K.S. Brinkman, L. Shuller-Nickles, “Atomistic scale investigation of cation ordering and phase stability in Cs-substituted Ba1.33Zn1.33Ti6.67O16, Ba1.33Ga2.66Ti5.67O16 and Ba1.33Al2.66Ti5.33O16 hollandite”, Scientific Reports, 2018, 8 (1), 5003.
S. Mu, Z. Zhao, J. Lei, Y. Hong, T. Hong, D. Jiang, Y. Song, W. Jackson, K.S. Brinkman, F. Peng, H. Xiao, J. Tong, “Engineering of microstructures of protonic ceramics by a novel rapid laser reactive sintering for ceramic energy conversion devices”, Solid State Ionics, 2018, 320, 369-377. PDF
H. zur Loye, T. Besmann, J. Amoroso, K. Brinkman, A. Grandjean, C. Heneger, S. Hu, S. Misture, S. Philpot, N. Shustova, H. Wang, R. Kock, G. Morrison, E. Dolgopolova, “Novel Approaches to Hierarchical Materials as Tailored Nuclear Waste Forms: A Perspective” Chemistry of Materials, 2018, 30, 4475-4488. PDF
T. Hong, Y. Zhang, K. Brinkman, “Enhanced Oxygen Electrocatalysis in Heterostructured Ceria Electrolyte for Intermediate Temperature Solid Oxide Fuel Cells” ACS OMEGA, 2018, 3, 13559-13566. PDF
E. Moore, V. Kocevski, C. Julillerat, G. Morrison, M. Zhao, K. Brinkman, H. zur-Loye, T. Besmann, “Understanding the Stability of Salt-Inclusion Phases for Nuclear Waste-forms through Volume-based Thermodynamics” Scientific Reports, 2018, 8, 15294. PDF
R. Grote, M. Zhao, L. Shuller-Nickles, J. Amoroso, W. Gong, K. Lilova, A. Navrotsky, M. Tang, K.S. Brinkman, “ Compositional control of tunnel features in hollandite- based ceramics: structure and stability of (Ba,Cs)1.33(Zn,Ti)8O16” Journal of Materials Science, 2018, 1-14. PDF
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2017
Tao Hong, Mingyang Zhao, Kyle Brinkman, Fanglin Chen and Changrong Xia, “Enhanced oxygen reduction activity on R-P phase decorated La0.8Sr0.2FeO3-δ 3D heterostructured cathode for solid oxide fuel cells” ACS Applied Materials and Interfaces, 2017, 9 (10), 8659-8668.
J. Amoroso, J. Marra, C. Dandeneau, K. Brinkman, Y. Yu, M. Tang, S. Webb, W. Chiu, “Cold Crucible Induction Melter Test of Crystalline Ceramic Waste forms: A Feasibility Assessment” Journal of Nuclear Materials, 2017 486, 283-297.
K. Reifsnider, F. Rabbi, V. Vadlamudi, MD. Raihan, K. Brinkman, “Critical Path-Driven Property and Performance Transitions in Heterogeneous Microstructures” Journal of Materials Science, 2017, 52:4796–4809. Highlighted on the Journal Cover.
C. Li, Y. Liu, J. He, K. S. Brinkman, “Ga-substituted Li7La3Zr2O12: an investigation based on grain coarsening in garnet type Li-ion conductors” Journal of Alloys and Compounds, 2017 695, 3744-3752.
T. Hong, S. Fang, M. Zhao, F. Chen, H. Zhang, S. Wang, K. Brinkman, “An intermediate-temperature oxygen transport membrane based on rare-earth doped bismuth oxide Dy0.08W0.04Bi0.88O2” Journal of the Electrochemical Society, 2017 164 (4), F347-F353.
Y. Xu, M. Zhao, K. Syed, H. Luo, K. Brinkman, “Self-substitution and the temperature effects on the electrochemical performance in the high voltage cathode system LiMn1.5+xNi0.5-xO4 (x=0.1)” Journal of Electrochemical Energy Conversion and Storage, 2017, 14, 021006-1-4.
Alex. P. Cocco, Matthew B. DeGostin, Jacob A. Wrubel, Peter J. Damian, Tao Hong, Yun Xu, Yijin Lin, Piero Pianetta, Jake Amoroso, Kyle S. Brinkman, and Wilson K. S. Chiu, “Three-dimensional mapping of crystalline ceramic waste form materials” Journal of the American Ceramic Society, 2017, 1-14. DOI: 10.1111/jace.14885.
T. Hong, S. Lee, P. Ohodnicki, K. Brinkman, “A highly scalable spray coating technique for electrode infiltration: Barium carbonate infiltrated La0.6Sr0.4Co0.2Fe0.8O3-δ perovskite structured electrocatalyst via spray coating” International Journal of Hydrogen Energy, 2017, 42 (39), 24978-24988.
F. Rabbi, K. Brinkman, J. Amoroso, and K. Reifsnider, “Finite Element analysis of ion transport in Solid State Nuclear Waste Form Materials” Journal of Nuclear Materials, 2017, 493, 303-309.
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2016
T. Hong, K. Brinkman, and C. Xia, “Barium Carbonate Nanoparticles as Synergistic Catalysts for the Oxygen Reduction Reaction on La0.6Sr0.4Co0.2Fe0.8O3-δ Solid-Oxide Fuel Cell Cathodes” ChemElectroChem, 2016, 3, 1-10.
Y. Xu, M. Feygenson, K. Page, L. Shuller-Nickles, K. Brinkman, “Structural Evolution in Hollandite Solid Solutions Across the A-site Compositional Range” Journal of the American Ceramic Society, 2016, 1-7, DOI: 10.1111/jace.14443.
Y. Xu, Y. Wen, R. Grote, J. Amoroso, L. Shuller-Nickles, K. Brinkman, “A-site compositional effects in Ga-doped hollandite materials of the form BaxCsyGa2x+yTi8-2x-yO16: implications for Cs immobilization in crystalline ceramic waste forms” Scientific Reports (Nature Publishing), 2016, 6, 27412; doi: 10.1038/srep27412.
T. Hong, K. Brinkman, C. Xia, “Copper oxide as synergistic catalyst for oxygen reduction reaction on La0.6Sr0.4Co0.2Fe0.8O3-δ electrocatalyst” Journal of Power Sources, 2016, 329, 281-289.
K. Brinkman and K. Huang, “Solid Oxide Fuel Cells and Membranes” Chemical Engineering Progress, 2016, 112 (7), 44-49.
A. Trofimov, C. Li, K. S. Brinkman, L.G. Jacobsohn, “Luminescence investigation of Ce incorporation in garnet-type Li7Li3Zr2O12” Optical Materials, 2017, 68, 7-10.
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2015
Lin, S. Fang, D. Su, K. Brinkman* and F. Chen*, “Enhancing grain boundary ionic conductivity in mixed ionic electronic conductors” Nature Communications, 2015, 6, 6824 DOI 10.1038/ncomms7824.
Wang, Y. Liu, J. He, F. Chen, K. Brinkman, “Spark-plasma-sintered Barium Zirconate Based Proton Conductors for Solid Oxide Fuel Cell and Hydrogen Separation Applications” International Journal of Hydrogen Energy, 2015, 40 (16), 5707–5714.
M. Clark, P. Tumurogoti, S.K. Sundaram, J.W. Amoroso, J.C. Marra, K.S. Brinkman, “Microstructure-Property Relations in Melt Processed and Spark Plasma Sintered Ceramic Waste Forms” Microscopy and Microanalysis, 2014, 20 (Supplement 3), 1932.
B. M. Clark, P. Tumurugoti, S. K. Sundaram, J. W. Amoroso, J. C. Marra, and K. S. Brinkman, “Microstructures of Melt Processed and Spark Plasma Sintered Ceramic Waste Forms” Metallurgical and Materials Transactions E, 2014, 1 (4), 341-348.
Wang, Y. Chen, L. Zhang, C. Ren, F. Chen, K. Brinkman, “Two-Step Reactive Aid Sintering of BaZr0.8Y0.2O3 Proton-Conducting Ceramics” Journal of Electronic Materials, 2015, DOI: 10.1007/s11664-015-4078-9.
K. Brinkman, “Multi-Phase Ceramic Composites as Hosts for Nuclear Waste”, The Journal of the Homeland Defense and Security Information Center, 2015, 2, 23-26.
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2014
Jake Amoroso, James C. Marra, Ming Tang, Fanglin Chen, Ye Lin, Dong Su, Kyle S. Brinkman, “Melt Processed Multiphase Ceramic Waste Forms for Nuclear Waste Immobilization” Journal of Nuclear Materials, 2014, 454 (1-3), 12-21.
S. Fang, K. Brinkman, F. Chen, “Hydrogen permeability and chemical stability of Ni-BaZr0.1Ce0.7Y0.1Yb0.1O3-δ membrane in concentrated H2O and CO2” Journal of Membrane Science, 2014, 467, 85-92.
S. Fang, K. Brinkman, F. Chen, “Unprecedented CO2-promoted hydrogen permeation in Ni-BaZr0.1Ce0.7Y0.1Yb0.1O3 membrane” ACS Applied Materials and Interfaces, 2014, 6 (1), 725-730.
Siwei Wang, Yan Chen, Shumin Fang, Lingling Zhang, Ming Tang, Ke An, Kyle S. Brinkman, Fanglin Chen, “Novel chemically stable complex perovskite proton conductor: Improved proton conductivity by tuning the cation ordering” Chemistry of Materials 2014, 26 (6), 2021-2029.
W. Harris*, K. S. Brinkman*, L. Ye, D. Su, A. Cocco, A. Nakajo, M. DeGostin, Y. Chen-Wiegart, J. Wang, F. Chen, Y. Chu, W. Chiu, Characterization of 3D Interconnected Microstructural Network in Mixed Ionic and Electronic Conducting Ceramic Composites, Nanoscale, 2014, 6, 4480. * These authors contributed equally to this work.
S. Fang, S. Wang, K. Brinkman, F. Chen, Sinteractive Ni-BaZr0.8Y0.2O3-δ composite membrane for hydrogen separation, Journal of Materials Chemistry A, 2014, 2, 5825.
C. James, K. S. Brinkman, J. Gray, J. Cortes-Concepcion, D. Anton, Fundamental Environmental Reactivity Testing and Analysis of the Hydrogen Storage Material 2LiBH4:MgH2, International Journal of Hydrogen Energy, 2014, 39 (3), 1371-1381.
L. Zhang, Y. Gong, K. Brinkman, T. Wei, S. Wang, K. Huang, Flux of silver-carbonate membranes for post-combustion CO2 capture: the effects of membrane thickness, gas concentration and time, Journal of Membrane Science, 2014, 455, 162-167.
L. Zhang, C. Yang, A. Frenkel, S. Wang, G. Xiao, K. Brinkman, F. Chen, Co-generation of Electricity and Chemicals from Propane Fuel in Solid Oxide Fuel Cells with Anode Containing Nano-Bimetallic Catalyst, Journal of Power Sources, 2014, 262, 421-428.
L. Zhang, F. Liu, K. Brinkman, K. Reifsnider, A. Virkar, Investigation of Gadolinia-Doped Ceria (GDC) Electrolyte by Electrochemical Impedance Spectroscopy, Journal of Power Sources, 2014, 247, 947-960.
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2013
J. Amoroso, K. Brinkman, M. Tang and J. Marra, Investigations into Melt Processed Waste Forms For Nuclear Waste Immobilization: Single Phase Cs Containing Hollandite Compositions of the form Ba1.0Cs0.3A2.3Ti5.7O16; A = Cr, Fe, Al, Journal of Alloys and Compounds, 2013, 548, 590-599.
S. Wang, M. Tang, K. Brinkman, F. Chen, Ion-irradiation Induced Reduction in Sr2Fe1.5Mo0.5O6-δ Perovskite, Nuclear Instrument & Methods in Physics Research Section B (NIMB), 2014, 326 (1), 298-302.
M. Tang, A.Kossoy-Simakov, G. Jarvinen, J. Crum, L. Turo, B. Riley, K. Brinkman, K. Fox, J. Amoroso, J. Marra, Radiation Stability Test on Multiphase Glass Ceramic and Crystalline Ceramic Waste Forms, Nuclear Instrument & Methods in Physics Research Section B (NIMB), 2014, 326 (1) 293-297.
L. Zhang, X. Huang, C. Qin, K. Brinkman, Y. Gong, S. Wang, K. Huang, First Spectroscopic Identification of Pyrocarbonate for High CO2 Flux Membranes Containing Highly Interconnected Three-Dimensional Ionic Channels, Journal of Physical Chemistry Chemical Physics, 2013, 15 13147.
S.Wang, M. Tang, L. Zhang, G. Xiao, K. Brinkman, F. Chen, Irradiation effect on the structure change for Sr2Fe1.5Mo0.5O6-δ perovskite ceramic, Journal of Alloys and Compounds, 2013, 578, 170-174.
K. Reifsnider, W. Chiu, K. S. Brinkman, Y. Du, A. Nakajo, F. Rabbi, Q.L. Liu, Multiphysics Design and Development of Heterogeneous Functional Materials for Renewable Energy Devices: the HeteroFoaM Story, Journal of The Electrochemical Society, 2013, 160 (4), F470-F481.
K.S. Brinkman, K.M. Fox, J.C. Marra, J. Reppert, J. Crum, M. Tang, Single Phase Melt Processed Powellite (Ba, Ca)MoO4 for the Immobilization of Mo-Rich Nuclear Waste, Journal of Alloys and Compounds, 2013, 551, 136-142.
S. Wang, L. Zhang, K. Brinkman, F. Chen, Two-step Sintering of Ultrafine-grained Barium Cerate Proton Conducting Ceramics, Electrochimica Acta, 2013, 87, 194-200.
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2012
S. Wang, L. Zhang, Z. Yang, L. Zhang, S. Fang, K.S. Brinkman, F. Chen, Two-step co-sintering method to fabricate anode-supported Ba3Ca1.18Nb1.82O9 proton conducting solid oxide fuel cells, Journal of Power Sources, 2012, 215, 221-226.
A.E. Mendez-Torres, M.J. Martinez-Rodriguez, K.S. Brinkman, D. Krementz, Enhanced Safeguards: The Role of Smart Functional Coatings for Tamper Indication, Journal of Nuclear Materials Management, 2012, Vol. XL, 4.
S. Sherman, J. Gray, K.S. Brinkman, K. Huang, Combustion-Assisted Carbon Dioxide Capture Using MECC Membrane, Journal of Membrane Science, 2012, 401, 323-332.
R. Krishna, T. Hayer, D. Krementz, G. Weeks, A. Mendez Torres, K. Brinkman, K. Mandal, Characterization of transparent conducting oxide thin films deposited on ceramic substrates, Materials Letters, 2012, 66, 233-235.
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2011
S. Wang, F. Zhao, L. Zhang, K. Brinkman, F. Chen, The doping effect on complex perovskite Ba3Ca1.18Nb1.92O9- intermediate temperature proton conductor, Journal of Power Sources, 2011, 196, 7917-7923.
K. S. Brinkman, E.B. Fox, P. Korinko, D. Missimer, T. Adams, The Role of Partial Crystallinity on Hydrogen Permeation in Fe-Ni-B-Mo based Metallic Glass Membranes, Journal of Membrane Science, 2011, 378 (1-2), 301-30.
C.W. James, D. Tamburello, K.S. Brinkman, J.R. Gray, B.J. Hardy, D.L. Anton, Environmental exposure of 2LiBH4+MgH2 using empirical and theoretical thermodynamics, International Journal of Hydrogen Energy, 2011, 36 (3) 2471-2477.
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2010
K. Brinkman, T. Iijima, H. Takamura, H. Tuller, The Preparation and Oxygen Permeation Properties of Nanocrystalline CeO2 Thin Films on Porous Cerium Oxide Substrates, Journal of the Electrochemical Society, 2010, 157 (12), B1852-B1857.
D.L. Anton, C.W. James, D. Tamburello, J. Cortes-Concepcion, J.R. Gray, K.S. Brinkman, Environmental Reactivity of Solid State Hydride Materials: Modeling and Testing for Air and Water Exposure, Advances in Science and Technology, 2010, 72, 219-229.
S. Wang, F. Zhao, L. Zhang, K. Brinkman, F. Chen, Stability and Electrical Property for Ba1-xSrxCe0.8Y0.2O3- High Temperature Proton Conductors, Journal of Alloys and Compounds, 2010, 506 (1), 263-267.
F. Zhao, S. Wang, K. Brinkman, F. Chen, Layered perovskite PrBa0.5Sr0.5Co2O5 as high-performance cathode for solid oxide fuel cells using proton conducting electrolyte, Journal of Power Sources, 2010, 195 (17), 5468-5473.
F. Zhao, Q. Liu, S. Wang, K. Brinkman, F. Chen, Synthesis and characterization of BaIn0.3-xYxCe0.7O3-d (x=0, 0.1, 0.2, 0.3) proton conductors, International Journal of Hydrogen Energy, 2010, 35 (9) 4258-4263.
K. Brinkman, T. Iijima, H. Takamura, The Oxygen Permeation Characteristics of Bi1-xSrxFeO3 Mixed Ionic and Electronic Conducting Ceramics, Solid State Ionics, 2010, 181 (1-2), 53-58.
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Older
S. Oosone, K. Brinkman, Y. Shimojo, T. Iijima, Ferroelectric and piezoelectric properties of Pb(ZrxTi1-x)O-3 thick films prepared by chemical solution deposition process, Thin Solid Films, 2008, 516 (12), 4325-4329.
K. Brinkman, Y. Wang, A. Tagantsev, D. Su, N. Setter, "The Impact of chemical ordering on the dielectric properties of lead scandium tantalate"
S. Oosone, Y. Shimojo, K. Brinkman, T. Iijima, K. Saito, "Direct observation of 90° domain switching in lead zirconate titanate thick films using x-ray diffraction."
K. Brinkman, T. Iijima, H. Takamura, "Acceptor Doped BiFeO3 Ceramics: A New Material for Oxygen Permeation Membranes."
K. Brinkman, T. Iijima, K. Nishida, T. Katoda, H. Funakubo, "The Influence of Acceptor Doping on the Structure and Electrical Properties of Sol-Gel Derived BiFeO3 Thin Films."
K. Brinkman, A. Tagantsev, P. Muralt, N. Setter, "Self Polarization in PbSc1/2Ta1/2O3 Relaxor Thin Films: Impact on the Dielectric and Piezoelectric Response".
V. Bovtun, S. Veljiko, S. Kamba, J. Petzelt, S. Vakhrushev, Y. Yakymenko, K. Brinkman, N. Setter, "Broad-band dielectric response of PbMg1/3Nb2/3O3 relaxor ferroelectrics: Single crystals, ceramics and thin films".
K. Brinkman, A. Tagantsev, V. Cherman, D. Su, N. Setter, "The In-Plane versus the out-of-plane dielectric response in the thin-film relaxor P(Sc1/2Ta1/2)O3".
S. Kamba, M. Kempa, V. Bovtun J. Petzelt, K. Brinkman, N. Setter, "Soft and central mode behaviour in PbMg1/3Nb2/3O3 relaxor ferroelectric".
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Patents
Xiao H.; Tong J.; Peng F.; Brinkman K.S.; Mu S.; LEI J.; Hong Y.; Huang H.; Bordia R. Integrated Additive Manufacturing and Laser Processing Systems and Methods for Ceramic, Glass, and Silicon Carbide Applications. US 20240408790A1, 2024.
Amoroso J.K.; Brinkman K.S.; Tong J.; Gao J.; Meng Y.; Becnel J.M. Nanostructured Ceramic Membranes for Hydrogen Isotope Separation. US 20230382769A1, 2023.
Hitchcock D.A.; Sekiz S.M.; Krentz T.M.; Velten J.A.; Brinkman K.S.; Vogel E.M.; Young K.T. Hydrogen Isotope Separation Systems. US20230017076A1, 2023.
Hitchcock D.A.; Sekiz S.M.; Krentz T.M.; Velten J.A.; Brinkman K.S.; Vogel E.M.; Young K.T. Hydrogen Isotope Separation Methods and Systems. US11433353B2, 2022.
Chen F.; Fang S.; Brinkman K.S.; Wang S.; He J.; Liu Y. Graphene-ceramic Composite Membrane for Hydrogen Separation Membranes. US10899613B2, 2021.
Chen F.; Fang S.; Brinkman K.S. Chemically Stable Ceramic-Metal Composite Membrane for Hydrogen Separation. US9687775B2, 2017.
Brinkman K.S.; Garcia-Diaz B.L.; Gray J.R. Electrochemical Cell for Recovery of Metals from Solid Metal Oxides. US20160032473A1, 2016.
Brinkman K.S. Nanocrystalline Cerium Oxide Materials for Solid Fuel Cell Systems. US9023550B2, 2015.
Brinkman K.S.; Korinko P.S.; Fox E.B.; Chen F. Proton Conducting Ceramics in Membrane Separations. US9005486B2, 2015.
